Congrats on your new hybrid limited! A couple of things to keep in mind. With a hybrid, the higher mpg takes place in the city, not the highway, where they have the opportunity to use the batteries more. Also, higher highway speeds will hurt gas mileage once you get above 55-60 mph. I have a gas XLE so I can't speak to the MPG experience you are having, but I can speak to the fuel tank capacity issue. Assuming a 17.2 gallon tank, 1/4 tank remaining would mean pumping 12.9 gallons into it. At 1/4 tank and 75-80 miles on the DTE meter, I usually pump right around, or just a hair shy of, 12 gallons (my habit is to fill up at 1/4 tank). So basically my fudge factor is around 1 gallon, which seems reasonable. Could be that the problem is more prevalent in the hybrid models.
Give the car a chance to break in, and verify the mileage the instrumentation is reporting with a manual MPG calculation. You'll find that the on-board instrumentation isn't 100% accurate. Also, basing your range expectations on tank size and EPA estimates may be overly optimistic. The other thing to keep in mind is depending on where you live you could be running on winter blend fuel. If that is the case your MPG will be significantly lower. Wait to make a judgement until you get the warm weather regular blend back.